期刊
SYNLETT
卷 -, 期 19, 页码 2879-2882出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1259038
关键词
catalysis; 1,4-dienes; allylation; allylsilanes; gold
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19750071]
- Grants-in-Aid for Scientific Research [19750071] Funding Source: KAKEN
The cationic gold(I)-catalyzed reaction of 1-alkynyl-2-allylsilylbenzenes with water results in intramolecular allylation of the alkynes via 7-exo-dig cyclization to give 1,4-dienes in good yield with excellent stereoselectivities.
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