期刊
SYNLETT
卷 -, 期 20, 页码 3355-3359出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1218373
关键词
ruthenium catalyst; regioselective addition; nitriles; 1,3-dicarbonyl compounds; alkynes
资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
RuH2(PPh3)(4)-catalyzed reaction of nitriles with terminal alkynes proceeds highly efficiently under neutral conditions to give the corresponding Michael adducts. Furthermore, 1,3-dicarbonyl compounds react with terminal alkynes at the alpha-position to afford the exo-methylene compounds with high regioselectivity under neutral conditions. The regioselectivity depends upon the change of substrates. The precise mechanism is presented.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据