4.4 Article

Palladium-Catalyzed Double Cross-Coupling Reaction of vic-Diborylalkenes and -arenes with vic-Bromo(bromomethyl)arenes

期刊

SYNLETT
卷 -, 期 19, 页码 3147-3150

出版社

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1218341

关键词

annulations; arenes; boron; bromine; cross-coupling

资金

  1. Ministry of Education. Culture, Sports, Science and Technology, Japan [16GS0209]
  2. The Asahi Glass Foundation

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Efficient annulation of vic-diborylalkenes and -arenes with vic-bromo(bromomethyl)arenes has been achieved, Using Pd(PPh(3))(4) as a catalyst in the presence of Cs(2)CO(3) and water ill THF at 60 degrees C, giving rise to the corresponding indene and fluorene derivatives in good to high yields.

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