期刊
SYNLETT
卷 -, 期 4, 页码 643-647出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1087926
关键词
heterogeneous catalysis; ionic liquids; click reaction; copper; supported catalysis
资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) [2003 1011]
Cuprous bromide was immobilized as a copper-supported ionic liquid catalyst (Cu-SILC) in the pores of amorphous mercaptopropyl silica gel with the aid of an ionic liquid, [bmim]PF(6). The heterogeneous Cu-SILC effectively and regioselectively catalyzed Huisgen [3+2] cycloadditions at room temperature in aqueous ethanol, and was used LIP to six times after simple decantation.
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