期刊
SYNLETT
卷 -, 期 2, 页码 233-236出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1087519
关键词
carbenes; diastereoselectivity; fused-ring systems; ring closure; umpolung
The use of a commercially available thiazolium salt facilitated an intramolecular Stetter reaction between an aliphatic aldehyde and an acrylate unit, which delivered a trans,syn-fused bicyclic pyranone in high yield as a single diastereomer. The pyranone was used to synthesize a trans,syn,trans-fused polycyclic ether array and was ring expanded to give the corresponding oxepanone.
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