期刊
SYNLETT
卷 -, 期 17, 页码 2659-2662出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1083510
关键词
electrophilic amination; asymmetric catalysis; bifunctional organocatalyst; alpha-cyanoketones
资金
- Ministry of Education, Science, Technology (MEST)
- Korea Industrial Technology Foundation (KOTEF)
The catalytic enantioselective electrophilic alpha-amination promoted by chiral bifunctional organocatalysts is described. Treatment of alpha-cyanoketones with azodicarboxylates as electrophilic amination reagents under mild reaction conditions afforded the corresponding alpha-aminated alpha-cyanoketones with excellent enantiomeric excesses (87-99%).
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