期刊
SYNLETT
卷 -, 期 14, 页码 2161-2163出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1078018
关键词
multicomponent reactions; Passerini reaction; phosphates; phosphorylation; prebiotic chemistry
资金
- Engineering and Physical Sciences Research Council
Monoalkyl phosphates can take the place of carboxylic acids in the Passerini reaction, but excesses of aldehyde an isonitriles are required, and transfer of the phosphate to the newly formed hydroxyl group does not take place. By rendering the phosphate addition intramolecular, the efficiency of the reaction is substantially increased. Phosphate transfer can take place when cyanovinyl phosphate is used rather than a monoalkyl phosphate.
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