期刊
SYNLETT
卷 -, 期 9, 页码 1279-1282出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-1072749
关键词
deuteration; CAN; oxidation; hydrazines; hydrazides
Aryl and heteroaryl hydrazines and hydrazides were successfully oxidised using CAN, deriving dehydrazinated products. The reaction pathway strongly depends on the nature of the substrate, resulting in the formation of hydrocarbons or alkoxy derivatives. When deuterated solvents such as methanol-d(4) or acetonitrile-d(3) were used, a regiospecific incorporation of deuterium was achieved.
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