期刊
SURFACE SCIENCE
卷 604, 期 1, 页码 11-20出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.susc.2009.10.008
关键词
Iron-oxide film; Reduction; Scanning tunneling microscopy; Water; Metal-oxide; X-ray photoelectron spectroscopy
资金
- Danish Research Agency
- Strategic Research Council and the Danish Council for Independent Research
- Carlsberg and Villum Kahn Rasmussen Foundations
- European Research Council
- DOE-BES
- Chemical Sciences Division
Using scanning tunneling microscopy (STM), X-ray photoemission spectroscopy (XPS) and density functional theory (DFT) calculations we have studied the reduction of ultra-thin films of FeO(1 1 1) grown on Pt(1 1 1) after exposure to atomic hydrogen at room temperature. A number of new ordered, partly-reduced FeOx structures are identified and as a general trend we reveal that all the reduced FeOx structures incorporate 2-fold coordinated Fe atoms as opposed to the original 3-fold coordinated Fe atoms in the FeO film We find that when all the Fe atoms are 2-fold O-coordinated the FeOx surface structure is resistant to further reduction at room temperature. We observe that water easily dissociates oil the most heavily reduced FeOx, structure in contrast to the initially inert FeO film. and reveal that it is possible to partially re-oxidize the FeOx film by heating the surface slightly in the presence of water (C) 2009 Elsevier B V. All rights reserved.
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