期刊
SURFACE SCIENCE
卷 603, 期 19, 页码 2964-2971出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.susc.2009.08.004
关键词
Halocarbon adsorption; Halobenzenes; Dipole interactions; Adsorption kinetics
资金
- National Science Foundation [CHE-0650453]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0909580] Funding Source: National Science Foundation
Differences are seen in the adsorption of 1,2-di-iodobenzene, 1,3-di-iodobenzene, and 1,4-di-iodobenzene on graphite, as a function of exposure, using core level photoemission. The isomer 1,3-di-iodobenzene exhibits significant differences from 1,2-di-iodobenzene, and 1,4-di-iodobenzene in apparent sticking coefficients and core level binding energies. 1,3-Di-iodobenzene adsorb on graphite at 110 K in a strongly Stranski-Krastanov or Volmer-Weber (island) growth mode. The implication is that, even for small molecules adsorption, the adsorbate dipole in the plane of surface and the choice of isomer may matter. (C) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据