期刊
SURFACE & COATINGS TECHNOLOGY
卷 203, 期 5-7, 页码 822-825出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2008.05.017
关键词
APGD; DBD; Plasma; Acid; Siloxane; XPS
A parallel plate dielectric barrier glow discharge operating at around atmospheric pressure was used to deposit functional coatings onto thin (<3 mm) sheets of steel. An organic precursor was introduced with helium into a mixing chamber connected to the plasma region. X-ray photoelectron spectroscopy showed that at high precursor flow rate and low power, the monomer was only slightly fragmented during the plasma process. Coatings containing a range of concentrations (12.6 to 29.7%) of carboxylate were prepared from acrylic acid. The surfaces with higher concentrations of carboxylates had low (<20 degrees) contact angles with water. Coatings with a range of concentrations of carbon, silicon and oxygen were prepared from octamethylcyclotetrasiloxane. Extremely hydrophobic coatings (contact angles >130 degrees) were produced using lower power and higher flow rate of octamethylcyclotetrasiloxane whereas relatively more hydrophilic coatings (contact angles 50 to 100 degrees) resulted when a lower flow rate of octamethylcyclotetrasiloxane was used. (C) 2008 Elsevier B.V. All rights reserved.
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