期刊
SUPRAMOLECULAR CHEMISTRY
卷 25, 期 1, 页码 54-59出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2012.721550
关键词
polydiacetylenes; alkylamines; intercalation; supramolecules; sensors
资金
- National Research Foundation of Korea [20110018602]
The structure of polydiacetylene (PDA) supramolecules offers carboxylic acid-terminated alkyl side-chains around a p conjugated polymer backbone. Exposure of these supramolecules to alkylamines induced disruption of the conjugated PDA backbone via intercalation as revealed by a colorimetric/fluorometric response. This response is demonstrated to be dependent on the length of the alkylamine, offering a new view on intercalation in PDA systems with respect to supramolecules. It is found that this critical carbon chain length of alkylamine required to induce a colour change response must be greater than the alkyl side-chain length of PDA in order to interact with the conjugated backbone. Intercalation of longer species is also found to induce supramolecule aggregation resulting in destabilised PDA suspensions.
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