期刊
SUPRAMOLECULAR CHEMISTRY
卷 25, 期 5, 页码 292-301出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2013.773331
关键词
calixarenes; asymmetric catalysis; Michael addition; nitroolefins; organocatalysis
资金
- Scientific and Technological Research Council of Turkey (TUBITAK)
- Necmettin Erbakan University
The synthesis of calix[4]arene-based chiral bifunctional primary aminethiourea catalysts has been described from p-tert-butylcalix[4]arene for the first time. The calix[4]arene-based catalysts were successfully applied to promote Michael addition of aldehydes with nitroalkenes affording preferentially the (R)- or (S)-adducts in high yields (up to 95%) and excellent enantioselectivities (up to 99% ees).
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