期刊
SUPRAMOLECULAR CHEMISTRY
卷 23, 期 7, 页码 501-508出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2011.556252
关键词
calixarene; calix[4]bis(spirodienone); p-TSA; biscalixarenes; CuAAC
资金
- Council of Scientific and Industrial Research (CSIR) [NWP 0023]
- Department of Science and Technology (DST), New Delhi
- UGC
The spiro rings of calix[4]bis(spirodienone) have been opened up using various bromofunctionalised alcohols employing a novel ipso nucleophilic substitution of tert-butyl groups by alkoxy groups. Additionally, a route has been paved towards the preparation of triazole-linked biscalixarene via the copper(I)-catalysed modern version of classical Huisgen 1,3-dipolar cycloaddition of alkynyl calixarene and azidocalixarene, derived from the above-mentioned bromo-substituted calixarene.
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