期刊
SUPRAMOLECULAR CHEMISTRY
卷 22, 期 11-12, 页码 704-709出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2010.500728
关键词
calixarenes; methylene-functionalised; synthesis
资金
- Israel Science Foundation [257/07]
The hexabromocalix[6]arene 5 reacts with p-tert-Bu-phenol, thymol and propargyl alcohol to afford the corresponding hexasubstituted methylene-functionalised calixarenes. The substituents at the bridges were further functionalised via acetylation or click chemistry. Reaction of the hexahydroxy derivative 10 with DAST afforded 11, a first example of a calixarene with all bridges monofluorinated.
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