期刊
CHEMPLUSCHEM
卷 80, 期 8, 页码 1255-1258出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201500206
关键词
electrochemistry; nanostructures; thin films; transition metals; synthesis design
资金
- MEXT of Japan [24750054, 25107510, 26110505, 26220801, 26708005, 26107510, 26620039, 15H00862, 15K13654, areas 2406, 2506, 2509]
- Ogasawara Foundation for the Promotion of Science Engineering
- Noguchi Institute
- Tokuyama Science Foundation
- Asahi Glass Foundation
- Murata Science Foundation
- Iketani Science and Technology Foundation
- Japan Prize Foundation
- Kao Foundation for Arts and Sciences
- Japan Association for Chemical Innovation
- MIKIYA Science and Technology Foundation
- Yazaki Memorial Foundation for Science and Technology
- Shorai Foundation for Science and Technology
- Kurata Memorial Hitachi Science and Technology Foundation
- Kumagai Foundation for Science and Technology
- Grants-in-Aid for Scientific Research [26107510, 26620039] Funding Source: KAKEN
The synthesis of palladium bis(dithiolene) complex nanosheets (PdDt) possessing a kagome-type lattice structure was performed via interfacial reaction between metal salt in aqueous phase and dithiolato ligand in organic phase. The PdDt nanosheets were characterised by AFM, STM, TEM revealing flat and sheet-like morphology; IR, UV spectroscopy show the corresponding coordination connectivity between metal and ligand, followed by powder X-ray diffraction and SAED, which determined nanosheets to be structurally similar to previously reported nickel bis(dithiolene) complex nanosheets NiDt.
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