期刊
STRUCTURAL CHEMISTRY
卷 21, 期 5, 页码 1085-1091出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11224-010-9649-z
关键词
Coordination polymer; Crystal structure; 1-phenyl-3-methyl-5-pyrazolone; Fluorescence; Thermal stability; Cyclic voltammetry
资金
- Jiangsu Provincial Educational Committee of China [07KJA15011]
- Jiangsu Key Laboratory of Marine Biotechnology of Huaihai Institute of Technology [2009HS06]
- Jiangsu-Marine Resources Development Institute [JSIMR09D02]
- Qing Lan Project of Jiangsu Province
A new Cd(II) coordination polymer, [Cd(PMP)(2)] (n) (1) [PMP = 1-phenyl-3-methyl-5-pyrazolone], has been synthesized by the reaction of Cd(CH3COO)(2)center dot 2H(2)O with PMP and characterized by elemental analysis, IR spectrum, fluorescence spectrum, UV-vis spectrum, TG-DTA, and electrochemical analysis. Single crystal X-ray diffraction reveals that the complex has a three-dimensional network. Each PMP acts as bidentate bridging ligand and each Cd(II) center is surrounded by two O atoms and two N atoms from four different PMP ligands to form distorted tetrahedral coordination geometry. The photoluminescence study shows the complex exhibited strong solid state blue fluorescent emission at room temperature, and the TG-DTA analysis demonstrated that it has highly thermal stability. Furthermore, the electrochemical property of the complex has been investigated for the first time in DMF by cyclic voltammetry, and the results showed that it has an irreversible process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据