期刊
STRUCTURAL CHEMISTRY
卷 20, 期 4, 页码 693-697出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11224-009-9464-6
关键词
pKa values; Peri effect; Heterocycles; Steric effect; Gas phase basicities; Enthalpy of formation
资金
- National Institutes of Health [1 R01 GM087738-01A1]
An explanation for the reported lower basicity of quinoline as compared with pyridine or isoquinoline has been provided. The competing roles of steric hindrance and solvation effects are discussed along with resonance stabilization of neutral molecules and related ions.
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