期刊
STEROIDS
卷 76, 期 10-11, 页码 949-966出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.steroids.2011.04.002
关键词
Olefin metathesis; Cross-metathesis; Ring-closing metathesis; Total synthesis; Hemisynthesis; Steroids
资金
- Ministry of Science and Higher Education [N N204 154936]
Over the past decade, ruthenium-mediated metathesis transformations, including cross-metathesis, ring-closing metathesis, enyne metathesis, ring-opening metathesis polymerization, and also tandem processes, belong to the most intensively studied reactions. Many applications of olefin metathesis in the synthesis of natural products have been recently described. Also in the field of steroid chemistry new methods of total synthesis and hemisynthesis based on metathesis reactions have been elaborated. Various biologically active compounds, e.g. vitamin D and hormone analogues, steroid dimers and macrocycles, etc. have been prepared using a variety of olefin-metathesis protocols. (C) 2011 Elsevier Inc. All rights reserved.
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