期刊
STARCH-STARKE
卷 66, 期 9-10, 页码 809-817出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/star.201400022
关键词
DSC; Fatty acid; High-pressure homogenization; Starch-lipid complex; X-ray
资金
- Science & Technology Council of Heilongjiang Province, China [C200804]
Aqueous mixtures of defatted corn starch and different fatty acids were heated and processed with high-pressure homogenization to form starch-lipid complexes. A variety of fatty acids with chain lengths of 12-18 carbons and with varying degrees of unsaturation were studied regarding their ability to form amylose-lipid complexes. Linoleic acid (65.7%) displayed the greatest complex forming ability with defatted corn starch, followed by lauric acid (63.2%), oleic acid (62.2%), myristic acid (61.2%), palmitic acid (59.8%), and stearic acid (54.6%). The XRD analysis showed that the complexes presented the well-known V-helical type diffraction. DSC was used to analyze the thermal properties. Based on the 85-110 degrees C transition temperature and the 60-95 degrees C synthesis temperature, the experimental complexes are less ordered type I complexes. The in vitro digestibility studies indicated that long-chain saturated fatty acids increased digestibility more than the short-chain saturated and unsaturated fatty acids when in complex with defatted corn starch.
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