期刊
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
卷 76, 期 -, 页码 65-69出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.sab.2012.06.027
关键词
ICP-MS; Detection efficiency; Microdroplets
类别
资金
- Deutsche Forschungsgemeinschaft
Experimental investigations of analyte atomization, ionization and diffusion processes in the inductively coupled plasma applying single droplet introduction and optical emission spectroscopy provide hints how to improve the detection efficiency of inductively coupled plasma mass spectrometry. It is discussed how the flow, amount and type of injector gas, the size of droplets injected, the analyte mass, and the sampler interface of the mass spectrometer determine the position of analyte atomization and ionization as well as the magnitude of radial analyte ion diffusion at the interface of the mass spectrometer applied. (c) 2012 Elsevier B.V. All rights reserved.
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