期刊
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
卷 65, 期 8, 页码 715-720出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.sab.2010.04.011
关键词
LIBS; Deuterium; Plume segregation; Laser plasma
类别
The plasma produced by the irradiation of a hydrogen and deuterium containing carbon fiber composite with infrared laser pulses of 4-ns pulse duration has been investigated. The experiments were carried out under argon at reduced pressure. Microscopic analyses of the irradiated sample surface were performed to measure the ablation depth. Time- and space-resolved optical emission spectroscopy was applied to characterize the evolution of spectral line emission as a function of time and distance from the surface. Particular attention was paid to the time-of-flight characteristics of the hydrogen and deuterium Balmer alpha spectral lines. According to the different atomic masses of both isotopes, the expansion of hydrogen into the low pressure argon atmosphere was found to be slightly faster than that of deuterium. The effect of plume segregation is pressure dependent and tends to increase the analytical signal of heavy atoms with respect to lighter ones during laser-induced breakdown spectroscopy. (C) 2010 Elsevier B.V. All rights reserved.
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