期刊
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
卷 63, 期 4, 页码 484-492出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.sab.2008.01.001
关键词
microfocus; natural analog; mu-XRD; mu-XRF
类别
Results from combined mu-XRF and mu-XRD investigations of a uranium-rich tertiary sediment from a nuclear repository natural analog site in Ruprechtov, Czech Republic, are reported. The goal of the investigations is to identify arsenopyrite from diffraction patterns obtained in As-rich areas of the sample. Arsenopyrite has been revealed to be present in the sediment as thin coatings on the surface of Fe nodules from previous mu-XANES results and observed linear dependencies between Fe and As(0) distributions obtained from mu-XRF measurements. In thin sections of the sediment investigated here we find, however, neither diffraction reflections expected for arsenopyrite nor for other As-sulfides. The As(O) phase is likely present in the form of very small grains, or it is amorphous. Statistical analysis of the mu-XRD data using unsupervised classification and principle component analysis from selected sample areas also indicate that pyrite and siderite, but no arsenopyrite, are the sole diffracting phases. That pyrite and siderite are found in the same sample is an indication that the pH of the sediment environment during diagenesis must have been neutral. This allows us to refine our hypothesis for the mechanism of uranium immobilization. (c) 2008 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据