期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 79, 期 3, 页码 661-665出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2011.03.054
关键词
44 '-Bis-(carboxyl phenylazo)-dibenzo-18-crown-6; Azo dye; Ratiometric; Colorimetric sensors; Recognition; Hg2+
类别
资金
- College outstanding young talent foundation of Anhui Province [2011SQRL148]
- West Anhui University [2009LW008]
A multifunctional dye, 4,4'-bis-(carboxyl phenylazo)-dibenzo-18-crown-6 dye (BCADC) was designed and prepared via diazotization and coupling reaction of dibenzo-18-crown-6 with p-amino benzoic acid. The dye, combining crown ether ring, azo and carboxyl group, exhibits well-defined Hg2+-selective ratiometric colorimetric behavior, with the maximum absorbance peak changing from 354 nm to 408 nm exclusively. Under the optimum conditions, the recognition to Hg2+ has a linear range of 2.5-58 x 10(-7) mol L-1 with a 0.9978 correlation coefficient. The method was applied to analyse 3 environmental water samples with a detection limit of 2.9 x 10(-8) mol L-1 and a relative standard deviation (R.S.D.) lower than 3.7% (n = 5). The action mechanism between BCADC and metal ions was discussed by means of Job's plots and theoretical calculations. (C) 2011 Elsevier B.V. All rights reserved.
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