期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 75, 期 3, 页码 1168-1170出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2009.12.086
关键词
Manganese; Oxygen evolving complex; ESI(+)-MS/MS; tptz
类别
资金
- Research Council of Sharif University of Technology
- National Elite Foundation
The mononuclear complex [Mn(tptz)(CH3COO)(OH2)(2)]NO3 (1) was investigated by electrospray ionization mass spectrometry in aqueous solution at pH 4.5. Electrospray ionization mass spectrometry shows that mononuclear and dinuclear manganese cationic species are present in solution, probably in equilibrium with neutral 1. An experiment showed that the most important reaction in the presence of oxone (2KHSO(5)center dot KHSO4 center dot K2SO4) is decoordination. (C) 2010 Elsevier B.V. All rights reserved.
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