期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 72, 期 2, 页码 260-268出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2008.09.017
关键词
S-Benzyldithiocarbazate; Benzothiazoline; Spectral studies; Anti-microbial activity; Organotin (IV) complexes
类别
资金
- CSIR
- U.G.C., New Delh
Microwave-assisted synthesis and characterization of the organotin (IV) complexes are reported. Trigonal bipyramidal and octahedral complexes of tin (IV) have been synthesized by the reaction of dimethyltin (IV) dichloride with 4-nitrobenzanilide-S-benzyldithiocarbazate ((LH)-H-1), 4-chlorobenzanilide-S-benzyldithiocarbazate ((LH)-H-2), 4-nitrobenzanilidebenzothiazoline ((LH)-H-3) and 4-chlorobenzanilidebenzothiazoline ((LH)-H-4). The complexes so formed were characterized by elemental analysis, conductance measurements, molecular weight determinations and spectral data viz. IR, UV-Visible, H-1 and C-13 NMR. The anti-microbial activities of the ligands and their corresponding organotin (IV) complexes have been screened against various strains of bacteria and fungi. Antifertility activity against male albino rats has also been reported. (c) 2008 Elsevier B.V. All rights reserved.
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