期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 71, 期 5, 页码 1704-1711出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2008.06.023
关键词
Synergism; Preferential solvation; Merocyanines; Solvent effects; Hydrophobicity; Hydrogen bonding
类别
资金
- Brazilian Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Capes
- FURB
The molar transition energy (E-T) polarity values for the solvatochromic probes 2,6-diphenyl-4-(2,4,6-triphenylpyridinium)phenolate (1), 4[(1-methyl-4-(1H)-pyridinylidene)-ethylidene]-2,5-cyclohexadien-1-one (2), and 4-[4-(dimethylamino)styryl]-1-methylpyridinium iodide (3) were collected in binary mixtures comprising chloroform and a hydrogen-bond accepting (HBA) solvent [dimethyl sulfoxide (DMSO), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), acetone or acetonitrile], aiming to investigate the ability of the chlorinated component to act as hydrogen-bond donating (HBD) solvent. Plots of E-T as a function of X-2, the mole fraction of chloroform, were obtained and the data were analysed to investigate the preferential solvation (PS) of each probe in terms of both solute-solvent and solvent-solvent interactions. For dyes 1 and 2 a strong synergistic behavior was observed for all mixtures studied, indicating that the dyes are preferentially solvated by complexes formed through hydrogen bonding between chloroform and the HBA component in the mixtures. A study of 1 in deuterated chloroform with an HBA component (DMF and DMA) demonstrated that while almost no differences occur with the DMF mixtures, the presence of deuterated chloroform in its mixtures with DMA increases the synergistic effect, suggesting that it interacts more strongly with DMA. making its mixtures more polar. These data were successfully fitted to a model based on solvent-exchange equilibria. The features of the mixtures with dye 3 revealed a very different profile in comparison with the other two dyes, which suggests that in mixtures containing chloroform, the microenvironment of the dye seems to be important in determining the contribution of the structure resonances responsible for the stability of the dye. (c) 2008 Elsevier B.V. All rights reserved.
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