期刊
SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN
卷 20, 期 -, 页码 219-224出版社
JAPAN ASSOC SOLVENT EXTRACTION
DOI: 10.15261/serdj.20.219
关键词
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资金
- Creative Research Center for Advanced Molecular Biochemistry, Strategic Development of Research Infrastructure for Private Universities
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22560754]
- Grants-in-Aid for Scientific Research [22560754] Funding Source: KAKEN
Supported ionic liquid membranes containing calixarenes as carriers have been developed for saccharide separation. We examined the liquid membrane separation of saccharides using a quaternary ammonium salt Aliquat 336 as the ionic liquid and calix[x]arenes (x=4, 6, 8) as the carriers. In the permeation experiments, we observed high facilitated transport for glucose permeation with calix[4,6]arenes and for fructose, arabinose and ribose permeations with calix[8]arene. From permeation experiments using various derivatives of saccharides, we found that the calix[4,6]arenes interact with the OH-1,2 and 3 units and that calix[8]arene interacts with cis-3,4-diols units of the saccharides. Calixarenes, which have different numbers of phenol units, are concluded to be effective carriers for saccharides permeation.
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