期刊
SOLID STATE IONICS
卷 247, 期 -, 页码 71-75出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ssi.2013.06.005
关键词
Crown ether; Polymer electrolyte; Conductivity; PALS
Polymer electrolyte (PEO:NH4I) has been complexed with dibenzo-24-crown-8 ether (DB24C8). The conductivity of the complexes has been measured as a function of the crown ether composition. The conductivity of this system is an order of magnitude higher than for the PEO:NH4I system. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) have been done to know about the thermal behaviour of the complexes. The conformational changes have been detected by Fourier transform infrared (FTIR) spectroscopy. Conductivity modification in the complexes has been explained by the chain-like formation in the complexes, increased amorphous phase and the enhanced free volume determined by positron annihilation lifetime spectroscopy (PALS). (C) 2013 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据