4.5 Article

Mixed conductivity and electrode properties of Mn-doped Bi-Sr-Fe-based perovskite-type oxides

期刊

SOLID STATE IONICS
卷 253, 期 -, 页码 211-216

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ELSEVIER
DOI: 10.1016/j.ssi.2013.09.056

关键词

Bi-Sr-Fe-based perovskite-type oxide; Mixed ionic and electronic conductor; SOFC cathode; Oxygen permeable membrane; Mn-doping effect

资金

  1. Next Generation World-Leading Researchers (NEXT Program) by the Japan Society for the Promotion of Science [GR011]

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The Fe-site of Bi0.7Sr0.3FeO3-delta (BSF) was doped with manganese to determine any changes in the charged defects and understand how this change affects the electrode properties of this material. The electrical conductivity and oxygen permeability results suggest that Mn-doping effectively improves the electronic compensation of BSF, which is energetically favored by ionic compensation. In terms of electrode properties, 50 mol% Mn-doped BSF (BSFM55) showed more than one order of magnitude greater electrode resistance than BSF, suggesting that kinetics related to ionic defects plays a more important role than electronic defects in determining the properties of Bi-Sr-Fe based perovskite oxides. (C) 2013 Elsevier B.V. All rights reserved.

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