期刊
SOLID STATE IONICS
卷 192, 期 1, 页码 304-307出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ssi.2010.08.019
关键词
All-solid-state battery; Lithium battery; LiMn2O4; Coating; Surface modification
资金
- Grants-in-Aid for Scientific Research [21246098] Funding Source: KAKEN
To improve the electrochemical performance of an all-solid-state In/80Li(2)S center dot 20P(2)S(5) (electrolyte)/LiMn2O4 cell, a lithium-titanate thin film was used to coat LiMn2O4. The interfacial resistance between LiMn2O4 and the electrolyte (measured after initial charging) decreased when the LiMn2O4 particles were coated with lithium-titanate. A cell with lithium-titanate-coated LiMn2O4 had a higher capacity than a cell with noncoated LiMn2O4 for current densities in the range 0.064 to 2.6 mA cm(-2). Additionally, a cell with coated LiMn2O4 retained 96% of the 10th-cycle reversible capacity at a current density of 0.064 mA cm(-2) after 50 cycles. (C) 2010 Elsevier B.V. All rights reserved.
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