期刊
SOLID STATE COMMUNICATIONS
卷 184, 期 -, 页码 34-39出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ssc.2013.12.003
关键词
Cobalt ferrite; Clystal structure; Dielectric properties
资金
- Anita Loya Innovation Funds
We report on the frequency (f=20 Hz-1 MHz) and temperature (T=300-973 K) dependent dielectric properties of hafnium (Elf) incorporated cobalt ferrite (CoF2-xHfxO4 (CFO-Hf); x=0.00-0.20). The dielectric constant (epsilon') of CFO-Flf is T-independent at T < 450 K, at which point increasing trend prevails. A grain bulk-boundary based two-layer model, where semiconducting-grains separated by insulating-grain boundaries, satisfactorily accounts for epsilon-T (> 450 K) variation. Correspondingly, electrical responses in impedance formalism are attributed to the grain and grain-boundary effects which also accounts for the observed two dielectric-relaxations. The results demonstrate that the dielectric phenomena in CFO-Hi can be tailored by tuning HI-concentration. (C) 2013 Elsevier Ltd. All rights reserved.
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