Effect of external fields on the switching current in PZT ferroelectric ceramics

The dependence of a switching current in lead zirconate titanate (PZT) ferroelectric ceramics on the temperature and an applied electrical field was investigated. It was found that temperature has a moderate contribution to the switching current values, but applied electric fields have significant effects on the values. Importantly, a relaxation of switching current on frequency was observed through this method. By a comparison investigation on PZT ceramics of different compositions non-180 degrees domain switching was found to be responsible for the relaxation. A function, the 'active potential of domains' was proposed to interpret the observed results from the viewpoint of energy. The results obtained provide a new understanding of domain process in ferroelectric ceramics that relaxation of domains is a collective motion of non-180 degrees domains. (C) 2009 Elsevier Ltd. All rights reserved.