期刊
SOLAR ENERGY
卷 84, 期 5, 页码 854-859出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.solener.2010.02.011
关键词
Composite ionic liquid electrolyte; Layered alpha-titanium phosphate; Photovoltaic performance
资金
- National Nature Science Foundation of China [50802051]
- National High Technology Research and Development Program of China [2006AA03Z218]
- China Postdoctoral Science Foundation [20060400055]
We reported a composite electrolyte prepared by incorporating layered alpha-titanium phosphate (alpha-TiP) into a binary ionic liquid of 1-propyl-3-methylimidazolium iodide (PMII) and 1-ethyl-3-methylimidazolium tetrafluoroborate (EmimBF(4)) (volume ratio, 13:7) electrolyte. The addition of alpha-TiP markedly improved the photovoltaic properties of dye-sensitized solar cells (DSSCs) compared to that without alpha-TiP. The enhancement was explained by improved diffusion of tri-iodide (I-3(-)) ions, suppressed electron recombination with I-3(-) in the electrolyte and increased lifetime of electrons in mesoscopic TiO2 film. (C) 2010 Elsevier Ltd. All rights reserved.
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