期刊
SOFT MATTER
卷 10, 期 27, 页码 4855-4862出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sm00479e
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资金
- NSFC [21173132]
- NSF for Distinguished Young Scholars of Shandong Province [JQ201303]
- Independent Innovation Foundation of Shandong University (IIFSDU) [2012TS001]
Two chiral enantiomers of histidine-derived amphiphilic gelators, (4R,6S)-UIPCA and (4S,6R)-UIPCA, were synthesized through Pictet-Spengler reaction and their gelation behaviors with different organic acids were investigated. Interestingly, the chiral enantiomers of UIPCA showed smart enantioselectivity for gelating tartaric acid enantiomers to form hydrogels with excellent mechanical strength. The TEM and SEM images demonstrated that the hydrogels were composed of networks by physical entanglement of nanofibers with high aspect ratios. The formation of nanofibers was considered to be driven by the interplay of hydrogen bonding, electrostatic attraction, and hydrophobic interaction, which was supported by XRD and FT-IR spectra. The hydrogels exhibited sensitive response to a series of external stimuli, such as temperature, metal ions, and host-guest interactions, to realize the reversible gel-sol transition. The property of the gelation was elaborated and the gelators were expected to find their applications in chiral discrimination.
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