期刊
SOFT MATTER
卷 9, 期 19, 页码 4738-4761出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sm27710k
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资金
- Army Research Office [W911NF-11-1-0251]
- Defense Threat Reduction Agency [HDTRA1-11-1-0019]
- National Science Foundation [CHE-1111000]
- National Institutes of Health [GM081655]
- Office of Naval Research [N00014-12-1-0452]
- Semiconductor Research Corporation [P13696]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1111000] Funding Source: National Science Foundation
Sum frequency generation (SFG) vibrational spectroscopy has been developed into an important technique to study surfaces and interfaces. It can probe buried interfaces in situ and provide molecular level structural information such as the presence of various chemical moieties, quantitative molecular functional group orientation, and time dependent kinetics or dynamics at such interfaces. This paper focuses on these three most important advantages of SFG and reviews some of the recent progress in SFG studies on interfaces related to polymer materials and biomolecules. The results discussed here demonstrate that SFG can provide important molecular structural information of buried interfaces in situ and in real time, which is difficult to obtain by other surface sensitive analytical techniques.
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