4.6 Article

Portrait of carbon nanotube salts as soluble polyelectrolytes

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SOFT MATTER
卷 7, 期 18, 页码 7998-8001

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sm05959a

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  1. Region Aquitaine, CNRS (BDIR)
  2. Agence Nationale de la Recherche (GRAAL)

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Soluble single-walled carbon nanotube (SWNT) salts have been synthesized with varying negative charges, and their saturation solubilities in DMSO measured. A thermodynamic model of the Gibbs free energy of dissolution, widely used for polyelectrolytes, reproduces the experimental results with striking agreement. SWNT salts appear as a paradigm of stiff polyelectrolytes.

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