期刊
SOFT MATTER
卷 7, 期 6, 页码 2449-2455出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0sm01262a
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资金
- Case School of Engineering
- Sherwin-Williams Company
- National Science Foundation [DMR-0804874, CBET-0828155, BRIGE EEC-0824333, MRI-0821515]
- Bayer Fellowship
- [W911QY-08-C-0142]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0821515] Funding Source: National Science Foundation
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [0824333] Funding Source: National Science Foundation
This article reports the synthesis of a diacetylene containing organogelator for the use as a nanoscale filler for mechanical enhancement in a polymer nanocomposite. The tensile storage modulus increased when the self-assembled nanostructures were incorporated into a polymer matrix. Below the glass transition temperature, a modest increase of the tensile storage modulus was observed, but above the glass transition temperature, almost a two order of magnitude increase at the highest filler loadings was found. Additionally, the presence of the self-assembled nanofibers, increased the tensile storage modulus greater than a similar filler that does not form 1D nanofibers highlighting the importance of self-assembly to the mechanical reinforcement.
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