期刊
ACS MACRO LETTERS
卷 4, 期 1, 页码 128-132出版社
AMER CHEMICAL SOC
DOI: 10.1021/mz500734c
关键词
-
资金
- National Science Foundation of China [21104039]
- National 973 Project [2011CB935700]
A novel multicomponent system has been constructed through the combination of Hantzsch reaction and reversible addition-fragmentation chain transfer (RAFT) polymerization in a one-pot manner. Compared to traditional stepwise methods, this one-pot system exhibits much more advantages to facilely and efficiently prepare well-defined poly(1,4-dihydropyridine)s (poly(1,4-DHP)s). A series of poly(1,4-DHP) derivatives have also been successfully prepared through this Hantzsch-RAFT system using different aldehydes as reactants, suggesting this system is a general and versatile approach to prepare well-defined functional polymers with 1,4-DHPs as side groups. Since 1,4-DHP derivatives are an important class of bioactive molecules in the pharmaceutical field, this simple method to prepare poly(1,4-DHP)s might have potential to prepare related functional polymers for biological and pharmaceutical applications.
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