期刊
ACS MACRO LETTERS
卷 4, 期 5, 页码 526-532出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.5b00131
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资金
- NSF through the UMass MRSEC [DMR-0820506]
- Center for Hierarchical Manufacturing [CMMI-10250220]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0820506] Funding Source: National Science Foundation
Chirality transfer from molecule to assembly is a ubiquitous process, occurring in every class of self-assembling materials, from. liquid crystals to biological matter. Yet, a basic understanding of the influence of molecular chirality on the mesoscopic assembly of block copolymers lags decades behind nearly all other aspects of their structure (e.g., chain composition, topology, stiffness, interactions). This Viewpoint highlights recent experimental and theoretical studies of mesochiral assemblies of chiral block copolymers that are beginning to shed light onto the necessary conditions for and principle outcomes of chirality transfer in block copolymer melts.
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