期刊
SOFT MATTER
卷 5, 期 11, 页码 2179-2182出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b823131a
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资金
- NSF [DMR-0753148]
- PIRE [OISE-0730243]
The reversible formation of ordered physical gels from stimuli-responsive ABA [A poly(N,N-dimethylacrylamide) (PDMA), B = poly(N-isopropylacrylamide) (PNIPAM)] triblock copolymers is investigated utilizing dynamic light scattering, small angle X-ray scattering, and low-shear rheometry. As the temperature is increased above the phase transition temperature of the PNIPAM segment, triblock copolymers under a critical molecular weight are capable of packing into body-centered cubic arrays. Rheometric tests indicate that the storage moduli of the gels at 50 degrees C are inversely related to the molecular weight of the polymer.
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