4.6 Article

Unusual salt effect on the lower critical solution temperature of hyperbranched thermoresponsive polymers

期刊

SOFT MATTER
卷 4, 期 10, 页码 1991-1994

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/b811012n

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资金

  1. National Natural Science Foundation of China [20704030]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20070056046]
  3. Open Fund for the Large Scale Instruments of Tianjin University [20070437, 20080402]

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Compared with linear thermoresponsive polymers hyperbranched ones having spheroid-like structure exhibited an unusual salt effect: a non-linear LCST decrease upon increasing the concentration of various salts such as NaCl, KCl or Na2SO4 has been observed. The LCST variation of such polymers was more sensitive to the presence of salt.

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