期刊
ACS MACRO LETTERS
卷 5, 期 1, 页码 99-102出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.5b00804
关键词
-
资金
- National Natural Science Foundation of China [21172249, 21472225]
Although a lot of covalent organic frameworks (COFs) have been constructed over the past 10 years, the topologies of COFs are still quite limited. In this work, we report one-step construction of a COF with an unprecedented topology from the combination of C-3-symmetrical and C-2-symmetrical building blocks. It contains two types of triangular micropores of different sizes and chemical environments: one is 11.3 angstrom and the other is 15.2 angstrom. The structure of the dual-pore COF was confirmed by powder X-ray diffraction (PXRD) investigation, nitrogen adsorption desorption study, and theoretical calculations.
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