4.6 Article

Enhanced photoluminescence of core-shell CoFe2O4/SiO2/Y2O3:Eu3+ composite by remanent magnetization

期刊

SMART MATERIALS AND STRUCTURES
卷 22, 期 12, 页码 -

出版社

IOP PUBLISHING LTD
DOI: 10.1088/0964-1726/22/12/125014

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资金

  1. National Natural Science Foundation of China [51002141, 21275131, 11374204]
  2. Qianjiang Talents Project of the Technology Office of Zhejiang Province, China [2011R10086]
  3. Key Project of the Chinese Ministry of Education [211055]

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A core-shell cobalt ferrite/silicon dioxide/europium ion-doped Y2O3 (CoFe2O4/SiO2/Y2O3:Eu3+) composite was synthesized by a facile layer-by-layer method. Magnetization of the composite under an external magnetic field of approximately 0.25 T enhanced the photoluminescence (PL) intensity by 56%. The remanent magnetization of the CoFe2O4 core increased the excited charge-transfer transition between O2- and Eu3+ in the Y2O3: Eu3+ shell, thus enhancing the probability of radiative transition (D-5(0)-> F-7(2)) of Eu3+ ions and leading to enhanced PL. Remanent magnetization is a noncontact, easy-to-operate technique with high growth amplitude and potential for practical application for smart display devices.

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