期刊
SMALL
卷 14, 期 35, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201802045
关键词
carbon nitride; crystallization process; heterojunction; metal-organic frameworks (MOFs); photocatalysis
类别
资金
- National Natural Science Foundation of China [41573096, 21707064]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_17R71]
- State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control
- Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control [2017B030301012]
In this research, bulk graphitic carbon nitride (g-C3N4) is exfoliated and transferred to the carbon nitride nanosheets (CNNSs), which are then coupled with MIL-88B(Fe) to form the hybrid. From the results of the powder X-ray diffraction, scanning electronic microscopy and thermogravimetric analysis, it is found that the doping of CNNSs on the surface of MIL-88(Fe) could maintain the basic structure of MIL-88B(Fe), and the smaller dimension of CNNSs might influence the crystallization process of metal-organic frameworks (MOFs) compared to bulk g-C3N4. Besides, the effects of the CNNSs incorporation on photocatalysis are also investigated. Through the photoluminescence spectra, electrochemical measurements, and photocatalytic experiments, the hybrid containing 6% CNNSs is certified to possess the highest catalytic activity to degrade methylene blue and reduce Cr(VI) under visible light. The improvement of the photocatalytic performance can be attributed to the matched energy level which favors the formation of the heterojunctions. Besides, it promotes the charge migration such that the contact between MOFs and CNNSs is more intimate, which can be inferred from the electronic microscopy images. Finally, a possible photocatalytic mechanism is put forward by the relative calculation and the employment of the scavengers to trap the active species.
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