期刊
SMALL
卷 14, 期 48, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201802767
关键词
electrocatalyst; first-principles calculation; nanofiber; N-doped graphene; perovskite oxides
类别
资金
- Mid-Career Researcher Program through the National Research Foundation of Korea - Ministry of Science, ICT and Future Planning [NRF-2018R1A2A1A05077532]
- National Natural Science Foundation of China [21706132]
- Natural Science Foundation of Jiangsu Province [BK20160834]
- Creative Materials Discovery Program through the NRF [2017M3D1A1040828]
Fabricating perovskite oxide/carbon material composite catalysts is a widely accepted strategy to enhance oxygen reduction reaction/oxygen evolution reaction (ORR and OER) catalytic activities. Herein, synthesized, porous, perovskite-type Sm0.5Sr0.5CoO3-delta hollow nanofibers (SSC-HF) are hybridized with cross-linked, 3D, N-doped graphene (3DNG). This rationally designed hybrid catalyst, SSC-HF-3DNG (SSC-HG), exhibits a remarkable enhancement in ORR/OER activity in alkaline media. The synergistic effects between SSC and 3DNG during their ORR and OER processes are firstly revealed by density functional theory calculations. It suggests that electron transport from 3DNG to O-2 and SSC increases the activity of electrocatalytic reactions (ORR and OER) by activating O-2, increasing the covalent bonding of lattice oxygen. This electron transfer-accelerated catalysis behavior in SSC-HG will provide design guidelines for composites of perovskite and carbon with bifunctional catalysts.
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