期刊
SMALL
卷 11, 期 11, 页码 1310-1319出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201401922
关键词
-
类别
资金
- NSFC [51202213]
- NSFHBP [B2012203043]
- CPSF [2013M530889, 2014T70230]
- EYSFHP [Y2012005]
- [CG2014003002]
In this work, MnO2/GO (graphene oxide) composites with novel multilayer nanoflake structure, and a carbon material derived from Artemia cyst shell with genetic 3D hierarchical porous structure (HPC), are prepared. An asymmetric supercapacitor has been fabricated using MnO2/GO as positive electrode and HPC as negative electrode material. Because of their unique structures, both MnO2/GO composites and HPC exhibit excellent electrochemical performances. The optimized asymmetric supercapacitor could be cycled reversibly in the high voltage range of 0-2 V in aqueous electrolyte, which exhibits maximum energy density of 46.7 Wh kg(-1) at a power density of 100 W kg(-1) and remains 18.9 Wh kg(-1) at 2000 W kg(-1). Additionally, such device also shows superior long cycle life along with similar to 100% capacitance retention after 1000 cycles and similar to 93% after 4000 cycles.
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