期刊
SMALL
卷 10, 期 11, 页码 2260-2269出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201303371
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类别
资金
- 973 Project [2012CB932303]
- National Natural Science Foundation of China [51172261]
A novel solvothermal-induced self-assembly approach, using colloid sol as precursor, is developed to construct monolithic 3D metal oxide/GS (graphene sheets) aerogels. During the solvothermal process, graphene oxide (GO) is highly reduced to GS and self-assembles into 3D macroscopic hydrogels, accompanying with in situ transformation of colloid sol to metal oxides. As a proof of concept, Fe2O3/GS aerogels are synthesized based on Fe(OH)(3) sol, in which GS self-assemble into an interconnected macroporous framework and Fe2O3 nanocrystals (20-50 nm) uniformly deposit on GS. Benefitting from the integration of macroporous structures, large surface area, high electrical conductivity, and good electrode homogeneity, the hybrid electrode manifests a superior rate capability (930, 660 and 520 mAh g(-1) at 500, 2000 and 4000 mA g(-1), respectively) and excellent prolonged cycling stability at high rates (733 mAh g(-1) during 1000 charge/discharge cycles at 2000 mA g(-1)), demonstrating its great potential for application in high performance lithium ion batteries. The work described here provides a versatile pathway to construct various graphene-based hybrid aerogels.
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