期刊
SCIENTIFIC REPORTS
卷 5, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/srep10279
关键词
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资金
- Global Frontier R&D Program of Center for Multiscale Energy Systems - National Research Foundation under the Ministry of Science, ICT Future, Korea [0420-20130104]
- Basic Science Research Program through National Research Foundation of Korea (NRF) - Ministry of Science, ICT Future [2011-0011225]
- Fusion Research Program for Green Technologies through National Research Foundation of Korea (NRF) - Ministry of Science, ICT Future [2012M3C1A1048863]
- KBSI grant [T35435]
The oxygen evolution reaction (OER) is considered a major bottleneck in the overall water electrolysis process. In this work, highly active manganese oxide nano-catalysts were synthesized via hot injection. Facile surface treatment generated Mn(III) species on monodisperse 10 nm MnO nanocrystals (NCs). Size dependency of MnO NCs on OER activity was also investigated. Surprisingly, the partially oxidized MnO NCs only required 530 mV @ 5 mA cm(-2) under near neutral conditions.
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