期刊
SEPARATION SCIENCE AND TECHNOLOGY
卷 48, 期 5, 页码 775-788出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2012.710888
关键词
adsorption; perfluorinated compound; porous structure; recovery; surface functional group
资金
- Chulalongkorn University
- Thailand Research Fund, Thailand [MRG5380172]
- National Nanotechnology Center (NANOTEC), The National Science and Technology Development Agency (NSTDA), Thailand of Chulalongkorn University [P-11-00985]
- Higher Education Research Promotion and National Research University Project of Thailand, Office of the Higher Education Commission [FW1017A]
The effects of porous structures and surface functional groups (silanol, 3-aminopropyltriethoxy, 3-mercaptopropyltrimethoxy, n-octyldichloroethoxy, and titanium substitution) on perfluorinated compounds (PFCs) adsorption and recovery were evaluated. The adsorption of PFCs on all adsorbents followed the pseudo-second-order model, and the adsorption rate was controlled by the pore diffusion, except for microporous zeofites and powder activated carbon (PAC). 3-aminopropyltriethoxy-grafted surface produced the highest PFCs adsorption capacities. Perfluorooctane sulfonic acid (PFOS) recovery from silica-based adsorbents (by ethanol extraction) efficiencies were higher than those of PAC and approached 100%. Hydrophobic organic functional groups can protect mesoporous structure from hydrolysis reactions in adsorption and solvent recovery processes. Supplemental materials are available for this article. Go to the publisher's online edition of Separation Science & Technology to view the free supplemental file.
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